Silicone rubber vs. fluoroelastomer rubber for tubing - What is The Difference?

Last Updated May 21, 2025

Silicone rubber tubing offers excellent flexibility, high temperature resistance up to 230degC, and biocompatibility, making it ideal for medical and food applications. Fluoroelastomer rubber tubing excels with superior chemical resistance, thermal stability up to 205degC, and durability in harsh environments, suitable for fuel and chemical transfer.

Table of Comparison

Property Silicone Rubber Tubing Fluoroelastomer (FKM) Rubber Tubing
Temperature Range -60degC to 230degC -20degC to 204degC
Chemical Resistance Good against ozone, UV, water, and some chemicals Excellent against oils, fuels, solvents, and acids
Flexibility High flexibility, ideal for dynamic applications Moderate flexibility, better for static sealing
Compression Set Moderate resistance to compression set Low compression set, excellent sealing retention
Durability Good weather and ozone resistance Superior chemical and heat aging durability
Cost Lower cost Higher cost
Common Applications Medical, food processing, and high-temp environments Fuel lines, chemical transfer, and automotive

Introduction to Silicone Rubber and Fluoroelastomer Rubber

Silicone rubber offers exceptional flexibility, high temperature resistance up to 230degC, and excellent biocompatibility, making it ideal for medical and food-grade tubing applications. Fluoroelastomer rubber, known for its superior chemical resistance and ability to withstand temperatures up to 300degC, is preferred in aggressive chemical environments and high-performance industrial tubing. Both materials provide durable solutions, but the selection depends on specific temperature, chemical exposure, and regulatory requirements for tubing.

Chemical Composition and Structure

Silicone rubber features a polysiloxane backbone with alternating silicon and oxygen atoms, providing excellent thermal stability and flexibility at low temperatures. Fluoroelastomer rubber, primarily composed of fluorinated hydrocarbon polymers like vinylidene fluoride and hexafluoropropylene, offers superior chemical resistance and durability against aggressive solvents, fuels, and oils. The distinct chemical structures result in silicone rubber excelling in biocompatibility and flexibility, while fluoroelastomer tubing is preferred for harsh chemical environments requiring enhanced resistance and longevity.

Temperature Resistance Comparison

Silicone rubber tubing excels in high-temperature resistance, typically withstanding continuous exposure up to 230degC, making it ideal for applications requiring flexibility at elevated temperatures. Fluoroelastomer rubber, such as Viton(r), offers superior temperature resistance with capabilities reaching up to 250-300degC and exceptional chemical resistance, suitable for harsh environments. Comparing both, fluoroelastomer tubing provides enhanced durability under extreme thermal and chemical conditions, while silicone tubing remains cost-effective and flexible for moderate high-temperature uses.

Chemical and Fluid Compatibility

Silicone rubber tubing offers excellent chemical resistance to water, oxygen, and many polar solvents, but degrades when exposed to hydrocarbons, oils, and strong acids. Fluoroelastomer rubber tubing provides superior resistance to a wide range of chemicals, including fuels, solvents, and aggressive acids, making it ideal for harsh fluid compatibility requirements. Fluoroelastomers maintain integrity in extreme environments where silicone may fail, particularly with hydrocarbons and high-temperature fluids.

Mechanical Properties and Durability

Silicone rubber offers excellent flexibility and high-temperature resistance up to 230degC, making it ideal for applications requiring repeated bending and moderate mechanical stress, while fluoroelastomer rubber exhibits superior chemical resistance and tensile strength with temperature tolerance ranging from -26degC to 205degC, suitable for harsh environments. In terms of durability, silicone rubber maintains elasticity and performance in extreme cold and retains stability over time, whereas fluoroelastomer tubing resists swelling, compression set, and degradation from fuels, oils, and solvents, ensuring long-term reliability in aggressive chemical exposures. Mechanical properties of silicone rubber include lower tear resistance but higher elongation at break, contrasted with fluoroelastomer's higher tensile strength and superior resistance to abrasion and aging, influencing selection based on specific operational demands.

Flexibility and Elasticity Differences

Silicone rubber tubing offers superior flexibility and elasticity, maintaining performance across a broad temperature range from -60degC to 230degC, making it ideal for applications requiring frequent bending and stretching. Fluoroelastomer (FKM) tubing, while less flexible, provides excellent chemical resistance and durability but typically exhibits reduced elongation and elasticity compared to silicone. The choice between silicone and fluoroelastomer tubing hinges on the need for flexibility and stretchability versus chemical resistance and dimensional stability under harsh conditions.

Applications in Tubing Industries

Silicone rubber tubing excels in medical, food, and pharmaceutical industries due to its excellent biocompatibility, flexibility, and high-temperature resistance up to 200degC. Fluoroelastomer rubber tubing is preferred in chemical processing, automotive, and aerospace sectors for its superior chemical resistance, excellent fuel and oil tolerance, and ability to function effectively in temperatures ranging from -40degC to 200degC. Both materials are critical in tubing applications requiring durability, but fluoroelastomers offer enhanced performance in aggressive chemical environments.

Cost Analysis: Silicone vs Fluoroelastomer

Silicone tubing generally offers a lower initial cost compared to fluoroelastomer rubber, making it a cost-effective option for applications requiring flexibility and moderate chemical resistance. Fluoroelastomer tubing, while more expensive upfront, provides superior resistance to extreme temperatures, chemicals, and fuels, potentially reducing long-term maintenance and replacement expenses. Evaluating total cost of ownership, fluoroelastomer may deliver better value in harsh environments despite higher material costs, whereas silicone serves well for budget-sensitive, less demanding uses.

Regulatory and Safety Considerations

Silicone rubber tubing complies with FDA 21 CFR 177.2600 for food and pharmaceutical applications, offering excellent biocompatibility and high temperature resistance up to 200degC. Fluoroelastomer tubing meets USP Class VI and FDA regulations 21 CFR 177.2600, providing superior chemical resistance and stability in aggressive environments, but operates effectively within a narrower temperature range of -20degC to 205degC. Both materials are non-toxic and resistant to microbial growth, making them suitable for medical and food-grade tubing where regulatory compliance and safety are critical.

Choosing the Right Tubing Material

Silicone rubber tubing offers excellent flexibility, high temperature resistance up to 200degC, and biocompatibility, making it ideal for medical, food, and pharmaceutical applications. Fluoroelastomer rubber tubing excels in chemical resistance, withstanding aggressive solvents, oils, and fuels, and operates reliably in temperatures ranging from -20degC to 200degC, suitable for automotive and industrial uses. Selecting the right tubing material depends on application requirements such as temperature range, chemical exposure, and mechanical durability to ensure optimal performance and longevity.

Silicone rubber vs. fluoroelastomer rubber for tubing - What is The Difference?

Infographic: Silicone rubber vs Fluoroelastomer rubber for Tubing



About the author. Kakani is a respected author and expert in materials for industrial and manufacturing applications. With years of experience in both research and industry.

Disclaimer.
The information provided in this document is for general informational purposes only and is not guaranteed to be complete. While we strive to ensure the accuracy of the content, we cannot guarantee that the details mentioned are up-to-date or applicable to all scenarios. Topics about Silicone rubber vs Fluoroelastomer rubber for Tubing are subject to change from time to time.

Comments

No comment yet