Hydrogenated styrene-butadiene rubber vs. fluoro rubber for chemical gloves - What is The Difference?

Last Updated May 21, 2025

Hydrogenated styrene-butadiene rubber (HSBR) offers excellent abrasion resistance and flexibility for chemical gloves, while Fluoro rubber (FKM) provides superior chemical resistance and heat stability. Fluoro rubber gloves are ideal for handling aggressive solvents and oils, whereas HSBR gloves are better suited for mechanical protection and moderate chemical exposure.

Table of Comparison

Property Hydrogenated Styrene-Butadiene Rubber (HSBR) Fluoro Rubber (FKM)
Chemical Resistance Good resistance to oils, fuels, and ozone; moderate against solvents Excellent resistance to chemicals, fuels, oils, and solvents
Temperature Range -40degC to 150degC -20degC to 200degC
Durability High abrasion resistance; moderate aging stability Excellent heat and aging resistance; superior durability
Flexibility Good flexibility at low temperatures Moderate flexibility, stiffer than HSBR
Cost Lower cost; economical for general use Higher cost; premium performance
Application in Chemical Gloves Suitable for moderate chemical exposure and flexible glove requirements Ideal for harsh chemical environments and extended glove lifespan

Introduction to Chemical Protective Gloves

Hydrogenated styrene-butadiene rubber (HSBR) offers excellent resistance to abrasion, heat, and certain chemicals, making it suitable for chemical protective gloves requiring durability and flexibility. Fluoro rubber (FKM) excels in chemical resistance against fuels, oils, and solvents, providing superior protection in harsh chemical environments. Both materials are critical in manufacturing gloves tailored to specific industrial chemical exposure risks, with selection depending on the type of chemicals handled.

Overview of Hydrogenated Styrene-Butadiene Rubber (HSBR)

Hydrogenated Styrene-Butadiene Rubber (HSBR) boasts enhanced chemical resistance and thermal stability compared to conventional SBR, making it ideal for chemical glove applications requiring durability against oils, solvents, and harsh environments. Its hydrogenation process reduces unsaturation, providing improved oxidative and ozone resistance, which extends glove lifespan under rigorous chemical exposure. HSBR's balanced elasticity and abrasion resistance enable gloves to maintain flexibility and protection, outperforming some traditional materials in industrial safety gear.

Overview of Fluoro Rubber (FKM)

Fluoro rubber (FKM) offers exceptional chemical resistance, particularly against oils, fuels, and solvents, making it ideal for chemical gloves requiring durability in harsh environments. Its high-temperature tolerance, typically up to 200degC, surpasses hydrogenated styrene-butadiene rubber (HSBR), enhancing performance in aggressive chemical handling. Fluoro rubber's low permeability to gases and excellent aging resistance ensure prolonged glove integrity and safety in industrial applications.

Chemical Resistance Comparison: HSBR vs Fluoro Rubber

Hydrogenated styrene-butadiene rubber (HSBR) offers moderate resistance to oils, acids, and alkalis but tends to degrade when exposed to strong solvents and high concentrations of chemicals. Fluoro rubber (FKM), known for its superior chemical resistance, excels against a broad range of aggressive chemicals, including hydrocarbons, fuels, oils, and high-temperature chemicals, maintaining integrity under extreme conditions. For chemical gloves, fluoro rubber provides enhanced protection and durability in harsh chemical environments compared to HSBR, which is better suited for less aggressive chemical exposure.

Temperature and Thermal Stability Differences

Hydrogenated styrene-butadiene rubber (HSBR) offers excellent thermal stability with a service temperature range typically between -50degC to 150degC, making it suitable for gloves exposed to moderate heat conditions. Fluoro rubber (FKM) surpasses HSBR in temperature resistance, maintaining structural integrity up to 230degC and exhibiting superior thermal aging and chemical resistance. For chemical gloves requiring high-temperature durability and extended exposure to aggressive chemicals, fluoro rubber provides enhanced performance compared to hydrogenated styrene-butadiene rubber.

Mechanical Strength and Flexibility

Hydrogenated styrene-butadiene rubber (HSBR) offers superior mechanical strength and excellent abrasion resistance, making it ideal for gloves requiring durability under stress. Fluoro rubber (FKM) provides exceptional flexibility and outstanding chemical resistance, particularly against oils, fuels, and solvents, which enhances glove performance in harsh chemical environments. While HSBR excels in tensile strength and tear resistance, fluoro rubber delivers better elongation and flexibility, balancing protection with comfort in chemical glove applications.

Permeation and Degradation Rates

Hydrogenated styrene-butadiene rubber (HSBR) exhibits lower chemical permeation rates and superior resistance to degradation by oils, fuels, and certain solvents compared to fluoro rubber (FKM), making HSBR suitable for gloves handling aggressive hydrocarbons. Fluoro rubber, while offering excellent resistance to a broader range of chemicals including acids, bases, and aromatic solvents, typically shows higher permeation rates and faster degradation in chlorinated solvents than HSBR. Selection between HSBR and fluoro rubber gloves depends on specific chemical exposure profiles, with HSBR preferred for hydrocarbon-rich environments and fluoro rubber favored for diverse chemical resistance needs despite slightly higher permeation rates.

Cost Efficiency and Availability

Hydrogenated styrene-butadiene rubber (HSBR) offers greater cost efficiency for chemical gloves due to its lower production expenses and widespread raw material availability compared to fluoro rubber, which is more expensive and limited in supply. HSBR provides adequate chemical resistance for many industrial applications, making it a budget-friendly option for users prioritizing cost without severely compromising protection. Fluoro rubber, while significantly more expensive, delivers superior resistance to aggressive chemicals and high temperatures, limiting its use to niche markets where performance outweighs cost and availability concerns.

Industrial Applications and Use Cases

Hydrogenated styrene-butadiene rubber (HSBR) offers excellent resistance to ozone, heat, and mechanical abrasion, making it ideal for chemical gloves used in industrial settings involving acids, alkalis, and organic solvents. Fluoro rubber (FKM) provides superior chemical resistance against fuels, oils, and aggressive chemicals, making it preferred for gloves in automotive, aerospace, and chemical manufacturing industries where hydrocarbon exposure is prevalent. Both materials ensure high durability and protection, but HSBR is favored for general chemical handling, whereas Fluoro rubber excels in specialized applications requiring enhanced resistance to harsh chemicals and extreme environments.

Choosing the Right Material for Chemical Gloves

Hydrogenated styrene-butadiene rubber (HSBR) offers exceptional resistance to oils, alkalis, and abrasions, making it suitable for chemical gloves used in environments with hydrocarbons and solvents. Fluoro rubber (FKM) provides superior chemical resistance against a broad spectrum of fuels, acids, and high temperatures, ideal for gloves exposed to aggressive chemicals and extreme conditions. Selecting the right material depends on the specific chemical exposure, temperature range, and mechanical durability required for optimal glove performance and protection.

Hydrogenated styrene-butadiene rubber vs. fluoro rubber for chemical gloves - What is The Difference?

Infographic: Hydrogenated styrene-butadiene rubber vs Fluoro rubber for Chemical glove



About the author. Kakani is a respected author and expert in materials for industrial and manufacturing applications. With years of experience in both research and industry.

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The information provided in this document is for general informational purposes only and is not guaranteed to be complete. While we strive to ensure the accuracy of the content, we cannot guarantee that the details mentioned are up-to-date or applicable to all scenarios. Topics about Hydrogenated styrene-butadiene rubber vs Fluoro rubber for Chemical glove are subject to change from time to time.

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