Silicone rubber offers excellent flexibility and temperature resistance up to 230degC, making it ideal for low to moderate temperature sealing applications. Fluoroelastomer provides superior chemical resistance and durability in harsh environments, withstanding temperatures up to 300degC, preferred for automotive and aerospace O-ring seals.
Table of Comparison
Property | Silicone Rubber | Fluoroelastomer (FKM) |
---|---|---|
Temperature Range | -60degC to 230degC | -26degC to 204degC |
Chemical Resistance | Good for water, ozone | Excellent for oils, fuels, solvents |
Compression Set | Moderate | Low, excellent sealing retention |
Durability | Good weathering, UV resistance | Superior chemical and heat resistance |
Cost | Lower cost | Higher cost |
Applications | Food, medical, low-temperature seals | Automotive, aerospace, chemical processing |
Introduction to O-Ring Materials
Silicone rubber and fluoroelastomer are two widely used materials for O-rings, each offering distinct chemical and temperature resistance properties. Silicone rubber provides excellent flexibility and resistance to extreme temperatures ranging from -60degC to 230degC, making it ideal for applications requiring biocompatibility and weather resistance. Fluoroelastomer, known for its superior resistance to chemicals, fuels, and high temperatures up to 250degC, is preferred in automotive, aerospace, and chemical processing industries where durability and chemical stability are critical.
Overview of Silicone Rubber O-Rings
Silicone rubber O-rings are prized for their excellent flexibility, wide temperature range (-60degC to 230degC), and resistance to ozone, weathering, and UV radiation, making them ideal for static sealing applications. They offer moderate chemical resistance but are not suitable for exposure to fuels, oils, or aggressive chemicals compared to fluoroelastomer O-rings. Silicone's superior elasticity and aging stability ensure long-lasting performance in food, medical, and electrical industries where non-reactivity and temperature resilience are critical.
Overview of Fluoroelastomer (FKM) O-Rings
Fluoroelastomer (FKM) O-rings offer superior chemical resistance and high-temperature stability compared to silicone rubber, making them ideal for demanding industrial applications such as automotive fuel systems and chemical processing. FKM O-rings maintain elasticity in temperatures ranging from -20degC to 200degC, with some formulations tolerating up to 250degC, while resisting oils, fuels, acids, and solvents. These attributes enhance durability, prevent swelling, and ensure reliable sealing performance under harsh environmental conditions.
Chemical Resistance Comparison
Silicone rubber O-rings offer excellent resistance to water, ozone, and extreme temperatures but have limited chemical resistance against oils, fuels, and solvents. Fluoroelastomer O-rings (FKM) provide superior chemical resistance, especially against hydrocarbons, acids, and aggressive chemicals, making them ideal for harsh environments. Choosing between silicone and fluoroelastomer depends on the specific chemical exposure and operating conditions of the application.
Temperature Resistance and Performance
Silicone rubber offers excellent temperature resistance, functioning effectively in a range from -60degC to 230degC, making it suitable for applications requiring flexibility at both high and low temperatures. Fluoroelastomers excel in chemical and oil resistance while maintaining stable performance in temperatures from -26degC to 204degC, making them ideal for harsh environments involving fuels and solvents. For O-rings, silicone is optimal for extreme temperature variations and non-aggressive media, whereas fluoroelastomer provides superior durability and chemical resistance under high-temperature exposure and aggressive fluids.
Physical Properties and Durability
Silicone rubber O-rings exhibit excellent flexibility and low-temperature resistance, maintaining elasticity from -60degC to 230degC, while Fluoroelastomer O-rings offer superior chemical and heat resistance, functioning effectively between -26degC and 204degC. Fluoroelastomer demonstrates higher tensile strength and compression set resistance, making it more durable in harsh environments with exposure to fuels, oils, and solvents. Silicone rubber excels in applications requiring high flexibility and thermal stability, whereas Fluoroelastomer provides enhanced longevity and resistance in aggressive chemical and high-temperature conditions.
Applications and Industry Use Cases
Silicone rubber O-rings are widely used in medical devices, food processing, and electronics industries due to their excellent flexibility, high temperature resistance up to 230degC, and biocompatibility. Fluoroelastomer O-rings excel in automotive, aerospace, and chemical processing sectors, offering superior chemical resistance, thermal stability up to 300degC, and durability in harsh environments. Both materials are critical in sealing solutions but are chosen based on specific application requirements like chemical exposure, temperature range, and regulatory compliance.
Cost Comparison and Availability
Silicone rubber O-rings typically have a lower cost compared to fluoroelastomer O-rings, making them a more budget-friendly choice for general sealing applications. Fluoroelastomer O-rings, known for their superior chemical and temperature resistance, are often more expensive due to complex manufacturing and premium raw materials. While silicone rubber is widely available and commonly stocked by suppliers, fluoroelastomer O-rings may have longer lead times and limited availability in specialized grades.
Selection Criteria for O-Rings
Selection criteria for O-rings between silicone rubber and fluoroelastomer primarily depend on chemical resistance, temperature range, and mechanical properties. Silicone rubber offers excellent flexibility and performance in low-temperature applications down to -60degC but has limited resistance to fuels and oils, making it suitable for general sealing under mild chemical exposure. Fluoroelastomers provide superior resistance to aggressive chemicals, high temperatures up to 200degC or more, and excellent compression set resistance, ideal for demanding automotive and aerospace sealing environments.
Conclusion: Choosing Between Silicone Rubber and Fluoroelastomer
Silicone rubber O-rings offer superior flexibility, excellent temperature resistance from -60degC to 230degC, and good compressibility, making them ideal for low-to-medium pressure applications and environments requiring ozone and UV resistance. Fluoroelastomer O-rings provide exceptional chemical resistance, withstanding aggressive fuels, oils, and solvents, and maintain functionality at higher temperatures up to 200degC, suitable for automotive, aerospace, and industrial sealing solutions. Selecting between silicone rubber and fluoroelastomer depends on the specific application's temperature range, chemical exposure, and mechanical demands, ensuring optimal sealing performance and longevity.

Infographic: Silicone rubber vs Fluoroelastomer for O ring