Fluorocarbon rubber vs. butyl rubber for diaphragm - What is The Difference?

Last Updated May 21, 2025

Fluorocarbon rubber offers superior chemical resistance and high-temperature stability compared to butyl rubber, making it ideal for diaphragms in aggressive chemical environments. Butyl rubber provides excellent gas impermeability and flexibility at low temperatures, suitable for applications requiring airtight seals under moderate thermal conditions.

Table of Comparison

Property Fluorocarbon Rubber (FKM) Butyl Rubber (IIR)
Chemical Resistance Excellent resistance to fuels, oils, and chemicals Good resistance to gases and chemicals but weaker against oils
Temperature Range -20degC to 205degC (-4degF to 401degF) -40degC to 120degC (-40degF to 248degF)
Gas Permeability Low permeability, suitable for high-integrity seals Very low permeability, ideal for gas retention
Flexibility Moderate flexibility, suitable for dynamic applications High flexibility, excellent for diaphragm movement
Durability High wear and ozone resistance Excellent aging and weather resistance
Cost Higher initial cost More cost-effective

Introduction to Diaphragm Materials

Fluorocarbon rubber (FKM) offers exceptional chemical resistance, high temperature tolerance up to 200degC, and excellent durability, making it suitable for diaphragms in aggressive environments. Butyl rubber (IIR) provides superior impermeability to gases, good flexibility at low temperatures, and resistance to weathering, ideal for diaphragms in sealing applications exposed to air and moisture. Choosing between fluorocarbon and butyl rubber diaphragms depends on the specific chemical exposure, temperature range, and mechanical requirements of the application.

Overview of Fluorocarbon Rubber (FKM)

Fluorocarbon rubber (FKM) offers exceptional chemical resistance, high-temperature stability up to 200degC, and excellent compatibility with aggressive fuels and oils, making it ideal for diaphragm applications exposed to harsh environments. Its low permeability to gases and superior abrasion resistance enhance the durability and reliability of diaphragms in automotive and industrial fluid control systems. Compared to butyl rubber, FKM demonstrates significantly improved resistance to solvents and heat, ensuring longer service life under demanding operational conditions.

Overview of Butyl Rubber (IIR)

Butyl rubber (IIR), a copolymer of isobutylene with isoprene, offers exceptional impermeability to gases and excellent resistance to chemicals, ozone, and weathering, making it highly suitable for diaphragm applications requiring durability and airtight sealing. Compared to fluorocarbon rubber, butyl rubber provides superior flexibility and cushioning, though it has lower heat and oil resistance. This elastomer's unique molecular structure ensures reliable performance in automotive, medical, and industrial diaphragms where slow gas diffusion and chemical stability are critical.

Chemical Resistance Comparison

Fluorocarbon rubber exhibits superior chemical resistance compared to butyl rubber, especially against fuels, oils, solvents, and acids, making it ideal for diaphragm applications in aggressive chemical environments. Butyl rubber provides good resistance to polar solvents and weathering but tends to degrade when exposed to oils, hydrocarbons, and high-temperature chemicals. For diaphragms requiring prolonged exposure to harsh chemicals, fluorocarbon rubber offers enhanced durability and performance stability.

Temperature Tolerance Analysis

Fluorocarbon rubber exhibits superior temperature tolerance, maintaining elasticity and chemical resistance from -20degC to 200degC, making it ideal for high-temperature diaphragm applications. Butyl rubber operates effectively within a narrower range, typically from -40degC to 120degC, but lacks the thermal stability needed for extended exposure to elevated temperatures. The enhanced heat resistance of fluorocarbon rubber ensures longevity and reliability in severe thermal environments, outperforming butyl rubber in high-temperature tolerance.

Mechanical Properties and Durability

Fluorocarbon rubber exhibits superior chemical resistance and high-temperature stability, maintaining elasticity and tensile strength up to 200degC, making it ideal for diaphragms exposed to aggressive environments. Butyl rubber offers exceptional gas impermeability and flexibility with good mechanical resilience but is limited to lower temperature ranges around 120degC. In terms of durability, fluorocarbon rubber provides enhanced resistance to oils, fuels, and solvents, resulting in longer life cycles for diaphragms in demanding applications compared to butyl rubber's excellent weather and ozone resistance.

Gas Permeability and Seal Performance

Fluorocarbon rubber exhibits significantly lower gas permeability compared to butyl rubber, making it ideal for applications requiring superior resistance to gas leakage in diaphragm seals. Its excellent chemical stability and high-temperature tolerance enhance seal performance in aggressive environments where butyl rubber may degrade faster. While butyl rubber offers good elasticity and cost-effectiveness, fluorocarbon rubber's superior barrier properties ensure prolonged durability and reliable sealing under dynamic pressure conditions.

Cost Efficiency of FKM vs IIR

Fluorocarbon rubber (FKM) offers superior chemical resistance and temperature stability compared to Butyl rubber (IIR), making it ideal for demanding diaphragm applications. Although FKM has a higher initial cost, its enhanced durability and longer service life reduce overall maintenance and replacement expenses, improving cost efficiency over time. In contrast, IIR provides a lower upfront cost but may incur higher long-term costs due to more frequent replacements in harsh environments.

Typical Industrial Applications

Fluorocarbon rubber diaphragms excel in chemical processing, automotive fuel systems, and aerospace due to their exceptional resistance to high temperatures, oils, fuels, and aggressive chemicals. Butyl rubber diaphragms are preferred in pharmaceutical, food processing, and water treatment industries where excellent impermeability to gases and steam resistance are critical. Both materials provide durable sealing solutions, but fluorocarbon's chemical inertness suits harsh industrial environments while butyl's flexibility and gas impermeability match sanitary and low-permeability applications.

Selection Guidelines for Diaphragm Use

Fluorocarbon rubber offers superior chemical resistance, high-temperature stability up to 200degC, and excellent impermeability, making it ideal for diaphragms in harsh chemical environments and aggressive fluids. Butyl rubber provides exceptional gas impermeability, good flexibility at low temperatures, and resistance to ozone and weathering, suited for diaphragms in applications involving refrigeration, air, and gases. Selection guidelines recommend fluorocarbon rubber for diaphragms exposed to hydrocarbons, oils, and solvents, while butyl rubber is preferred for fuel systems, air handling, and environments requiring high elasticity and low gas permeability.

Fluorocarbon rubber vs. butyl rubber for diaphragm - What is The Difference?

Infographic: Fluorocarbon rubber vs Butyl rubber for Diaphragm



About the author. Kakani is a respected author and expert in materials for industrial and manufacturing applications. With years of experience in both research and industry.

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The information provided in this document is for general informational purposes only and is not guaranteed to be complete. While we strive to ensure the accuracy of the content, we cannot guarantee that the details mentioned are up-to-date or applicable to all scenarios. Topics about Fluorocarbon rubber vs Butyl rubber for Diaphragm are subject to change from time to time.

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