Bromobutyl rubber vs. butyl rubber for tire inner linings - What is The Difference?

Last Updated May 21, 2025

Bromobutyl rubber offers superior air impermeability and enhanced chemical resistance compared to standard Butyl rubber, making it ideal for tire inner linings requiring long-term durability and airtightness. Butyl rubber provides excellent flexibility and good impermeability but lacks the enhanced ozone and heat resistance characteristics of Bromobutyl rubber.

Table of Comparison

Property Bromobutyl Rubber (BIIR) Butyl Rubber (IIR)
Composition Isobutylene with brominated isoprene Isobutylene with isoprene
Air Permeability Lower permeability, excellent air retention Good air retention, higher permeability than BIIR
Chemical Resistance Improved resistance to ozone and chemicals Good chemical and ozone resistance
Adhesion Enhanced adhesion to other rubber compounds and metals Lower adhesion, may require adhesives
Flexibility & Damping Excellent flexibility; superior damping properties Good flexibility; moderate damping
Temperature Resistance Operates effectively from -40degC to 120degC Operates effectively from -50degC to 100degC
Price Higher cost due to halogenation process Lower cost, widely available
Applications Preferred for tire inner liners demanding superior air retention and durability Used in general tire inner liners, tubes, and other sealing applications

Introduction to Tire Inner Linings

Tire inner linings require materials with superior air retention and chemical resistance to maintain tire pressure and enhance durability. Bromobutyl rubber, a halogenated form of butyl rubber, offers improved curing characteristics and better adhesion to tire components compared to traditional butyl rubber. Both materials provide excellent impermeability, but bromobutyl's enhanced thermal stability and resistance to ozone make it preferred for high-performance tire inner linings.

Overview of Butyl Rubber

Butyl rubber, a homo-polymer of isobutylene with small amounts of isoprene, offers excellent impermeability to gases, making it ideal for tire inner linings. Its superior air retention, elasticity, and resistance to heat and chemicals extend tire durability and performance. Compared to bromobutyl rubber, butyl rubber provides reliable sealing but has lower halogen content, which affects curing speed and ozone resistance.

Properties of Bromobutyl Rubber

Bromobutyl rubber exhibits enhanced chemical resistance, excellent air impermeability, and superior heat aging properties compared to standard butyl rubber, making it ideal for tire inner linings. Its halogenation improves compatibility with curing agents, resulting in faster vulcanization and stronger cross-linking, which enhances durability. These properties ensure bromobutyl rubber tires maintain air pressure longer and perform better under high-temperature conditions.

Key Differences Between Butyl and Bromobutyl Rubber

Bromobutyl rubber exhibits superior air impermeability and enhanced resistance to heat and weathering compared to butyl rubber, making it ideal for tire inner linings requiring extended durability. Butyl rubber offers excellent impermeability and flexibility but has lower chemical resistance and heat stability than bromobutyl. The presence of bromine in bromobutyl rubber improves vulcanization speed and adhesion properties, resulting in better overall performance in tire inner liners.

Air Retention Capabilities

Bromobutyl rubber offers superior air retention capabilities compared to standard butyl rubber due to its enhanced impermeability and reduced gas permeability. The presence of bromine atoms in bromobutyl rubber improves its resistance to air diffusion, resulting in longer tire inflation retention and reduced pressure loss. This makes bromobutyl the preferred choice for tire inner linings requiring extended air retention performance and durability.

Resistance to Heat and Oxidation

Bromobutyl rubber exhibits superior resistance to heat and oxidation compared to standard butyl rubber, making it more suitable for tire inner linings exposed to high temperatures. The bromine atoms in bromobutyl enhance its thermal stability and oxidative durability, reducing degradation and extending tire lifespan. This improved resistance also benefits tire performance under extreme conditions, contributing to safer and longer-lasting inner liners.

Impact on Tire Performance and Longevity

Bromobutyl rubber offers superior air retention and enhanced impermeability compared to standard butyl rubber, significantly improving tire inflation consistency and reducing maintenance needs. Its increased resistance to heat buildup and chemical degradation extends the tire's lifespan by minimizing cracking and aging effects. Consequently, tires with bromobutyl inner linings exhibit better overall performance, durability, and reliability under diverse driving conditions.

Manufacturing and Processing Considerations

Bromobutyl rubber offers superior curing speed and improved adhesion properties compared to butyl rubber, enhancing manufacturing efficiency for tire inner linings. Its compatibility with sulfur-based curing systems allows more straightforward processing and better cross-link density, resulting in enhanced air retention and durability. Butyl rubber, while cost-effective, requires longer vulcanization times and shows lower compatibility with common curing agents, potentially increasing production cycles and energy consumption.

Cost Implications and Market Availability

Bromobutyl rubber offers enhanced air retention and resistance to heat and chemicals compared to traditional butyl rubber, leading to longer tire inner lining lifespan but at a higher production cost. Butyl rubber remains the more cost-effective choice due to its widespread availability and lower raw material expenses, making it popular for mass-market tire manufacturing. Market availability favors butyl rubber with established global supply chains, while bromobutyl rubber is less common but growing in demand for high-performance tire applications.

Choosing the Right Rubber for Tire Inner Linings

Bromobutyl rubber offers superior air retention and improved heat resistance compared to traditional butyl rubber, making it ideal for high-performance tire inner linings. Its enhanced impermeability to gases reduces tire pressure loss, contributing to longer service life and better fuel efficiency. Choosing bromobutyl rubber can optimize tire durability and safety, especially in demanding driving conditions.

Bromobutyl rubber vs. butyl rubber for tire inner linings - What is The Difference?

Infographic: Bromobutyl rubber vs Butyl rubber for Tire inner lining



About the author. Kakani is a respected author and expert in materials for industrial and manufacturing applications. With years of experience in both research and industry.

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