Polyether ether ketone (PEEK) offers superior chemical resistance, high-temperature stability up to 250degC, and excellent wear resistance compared to polyoxymethylene (POM), making it ideal for high-performance gear applications. Polyoxymethylene provides good mechanical strength and low friction but has a lower thermal limit around 100degC, suitable for standard gear operations.
Table of Comparison
Property | Polyether Ether Ketone (PEEK) | Polyoxymethylene (POM) |
---|---|---|
Mechanical Strength | High tensile and impact strength | Moderate tensile strength, good stiffness |
Wear Resistance | Excellent wear and abrasion resistance | Good wear resistance, but lower than PEEK |
Operating Temperature | Up to 260degC continuous use | Up to 100degC continuous use |
Chemical Resistance | Outstanding resistance to chemicals and solvents | Good chemical resistance, sensitive to strong acids and bases |
Moisture Absorption | Low moisture uptake | Low to moderate moisture absorption |
Dimensional Stability | High dimensional stability under load and temperature | Good dimensional stability, can deform under stress |
Cost | High - premium engineering polymer | Low to moderate - cost-effective for general applications |
Typical Gear Applications | High-performance, high-temperature, and high-load gears | Standard gears, low to moderate load and temperature |
Introduction: PEEK vs POM for Gear Applications
Polyether ether ketone (PEEK) offers superior mechanical strength, high-temperature resistance, and chemical stability compared to Polyoxymethylene (POM), making it ideal for demanding gear applications exposed to harsh environments. POM provides excellent dimensional stability, low friction, and cost-effective manufacturing, suitable for gears in less aggressive conditions or where weight reduction is critical. Selecting PEEK vs POM for gears depends on operational stresses, temperature ranges, and wear resistance requirements inherent to the specific industrial application.
Material Properties: Polyether Ether Ketone (PEEK) Overview
Polyether Ether Ketone (PEEK) exhibits exceptional mechanical strength, chemical resistance, and thermal stability, making it ideal for high-performance gear applications requiring durability under harsh conditions. Its high melting point around 343degC and excellent wear resistance outperform Polyoxymethylene (POM), which has lower thermal resistance and is prone to deformation under heavy loads. PEEK's low friction coefficient and superior fatigue resistance contribute to longer gear lifespan, especially in demanding environments.
Material Properties: Polyoxymethylene (POM) Overview
Polyoxymethylene (POM) is a high-performance engineering thermoplastic known for its excellent dimensional stability, low friction, and high stiffness, making it ideal for precision gear applications. Its superior wear resistance and low moisture absorption ensure long-lasting performance in dynamic mechanical environments compared to Polyether ether ketone (PEEK). The inherent toughness and chemical resistance of POM support efficient, low-noise gear operations under moderate temperature ranges up to 100degC.
Mechanical Strength Comparison: PEEK vs POM
Polyether ether ketone (PEEK) exhibits superior mechanical strength compared to Polyoxymethylene (POM), with tensile strength ranging from 90 to 100 MPa versus POM's typical 60 to 70 MPa. PEEK maintains its structural integrity at higher temperatures, operating effectively up to 250degC, while POM's maximum service temperature is around 100degC, making PEEK more suitable for high-stress, high-temperature gear applications. Additionally, PEEK offers better wear resistance and fatigue strength, enhancing gear durability under heavy loads and cyclic stress.
Wear and Friction Performance in Gear Systems
Polyether ether ketone (PEEK) exhibits superior wear resistance and lower friction coefficients compared to polyoxymethylene (POM) in gear systems, making it ideal for high-load and high-temperature applications. PEEK's inherent thermal stability and mechanical strength contribute to prolonged gear lifespan and consistent performance under demanding conditions. In contrast, POM gears demonstrate higher wear rates and friction, which can lead to more frequent maintenance and reduced efficiency in precision gear applications.
Chemical Resistance: Suitability for Harsh Environments
Polyether ether ketone (PEEK) offers superior chemical resistance compared to polyoxymethylene (POM), making it highly suitable for gears operating in harsh environments with exposure to aggressive chemicals. PEEK withstands strong acids, alkalis, and organic solvents without degradation, ensuring long-term durability and performance. In contrast, POM's chemical resistance is limited, particularly against strong oxidizing agents and solvents, which can lead to material swelling or brittleness.
Thermal Stability and Operating Temperature Range
Polyether ether ketone (PEEK) exhibits superior thermal stability compared to Polyoxymethylene (POM), maintaining structural integrity at continuous operating temperatures up to 250degC, whereas POM typically withstands temperatures only up to 100degC before degradation. The high glass transition temperature of PEEK (approximately 143degC) and melting point near 343degC enable it to endure elevated thermal environments without deformation, making it ideal for gears requiring prolonged heat resistance. In contrast, POM's lower thermal threshold limits its use in high-temperature applications, where thermal stability and resistance to thermal cycling are critical for gear longevity and performance.
Machinability and Processing Considerations
Polyether ether ketone (PEEK) offers superior machinability for gears due to its high thermal stability and resistance to wear, allowing precision cutting and fine tolerances. Polyoxymethylene (POM), while easier to machine at lower temperatures, may experience deformation under high thermal loads, limiting its use in high-performance gear applications. Processing PEEK requires higher processing temperatures (around 343degC) and specialized equipment, whereas POM processes at lower temperatures (around 175degC), offering cost-effective manufacturing but with trade-offs in mechanical robustness and thermal endurance.
Cost and Economic Feasibility
Polyether ether ketone (PEEK) offers superior mechanical strength and chemical resistance for gears but comes at a significantly higher cost compared to polyoxymethylene (POM), making it less economically feasible for large-scale or budget-sensitive applications. POM provides excellent wear resistance and low friction at a fraction of the price, making it a more cost-effective choice for most standard gear manufacturing needs. For applications requiring high performance and durability under extreme conditions, the investment in PEEK can be justified despite its premium price.
Best Use Cases: Selecting the Right Material for Gears
Polyether ether ketone (PEEK) excels in high-performance gear applications requiring exceptional chemical resistance, high-temperature stability up to 260degC, and outstanding mechanical strength, making it ideal for aerospace and automotive gears exposed to harsh environments. Polyoxymethylene (POM), also known as acetal, offers excellent dimensional stability, low friction, and good wear resistance at lower operating temperatures, well-suited for precision gears in consumer electronics and general machinery. Choosing between PEEK and POM depends on operational demands such as temperature range, load capacity, and environmental exposure, ensuring optimal gear longevity and performance.

Infographic: Polyether ether ketone vs Polyoxymethylene for Gear