Polyvinyl chloride vs. polyvinylidene chloride for food wrap - What is The Difference?

Last Updated May 21, 2025

Polyvinyl chloride (PVC) offers excellent clarity and stretchability for food wrap, while Polyvinylidene chloride (PVDC) provides superior barrier properties against oxygen and moisture, enhancing food preservation. PVDC-based wraps outperform PVC in maintaining freshness but may incur higher costs and involve more complex recycling processes.

Table of Comparison

Property Polyvinyl Chloride (PVC) Polyvinylidene Chloride (PVDC)
Common Use Food wrap, cling film, packaging Food wrap, barrier packaging, shrink wrap
Transparency Clear, high transparency Very clear, glossy finish
Barrier Properties Moderate moisture and gas barrier Excellent moisture, oxygen, and aroma barrier
Flexibility Good flexibility, clingy Less flexible, stronger and tougher
Toxicity / Safety Contains plasticizers; potential concerns in food contact Generally considered safer; minimal plasticizers
Heat Resistance Good up to ~60degC Higher heat resistance, suitable for cooking films
Environmental Impact Hard to recycle; persistent plastic More resistant; recycling limited but better barrier reduces food waste
Cost Lower cost, widely available Higher cost due to superior barrier

Introduction to Food Wrap Materials

Polyvinyl chloride (PVC) and polyvinylidene chloride (PVDC) are prominent polymers used in food wrap materials, each offering distinctive barrier properties. PVC provides flexibility and clarity but has moderate resistance to moisture and gases, making it suitable for short-term food storage. PVDC excels with superior oxygen and moisture barrier capabilities, extending shelf life and preserving food freshness more effectively in comparison to PVC.

Overview of Polyvinyl Chloride (PVC)

Polyvinyl Chloride (PVC) is a widely used polymer in food wrap applications due to its excellent clarity, flexibility, and barrier properties against moisture and gases. Its chemical structure provides durability and resistance to oils and fats, making it suitable for preserving the freshness of various food products. PVC food wraps are also valued for their cost-effectiveness and ease of sealing, which enhances food storage efficiency.

Overview of Polyvinylidene Chloride (PVDC)

Polyvinylidene Chloride (PVDC) is a highly effective barrier material used in food wrap due to its superior resistance to oxygen, moisture, and aromas, which helps in extending the shelf life of perishable products. PVDC films offer excellent clarity, flexibility, and chemical stability, making them ideal for packaging sensitive foods such as meats and cheeses. Compared to Polyvinyl Chloride (PVC), PVDC provides enhanced protection against contamination and spoilage, ensuring food freshness and safety.

Barrier Properties: Oxygen and Moisture Protection

Polyvinyl chloride (PVC) provides moderate oxygen and moisture barrier properties, making it suitable for short-term food wrap applications. Polyvinylidene chloride (PVDC) offers superior barrier protection, significantly reducing oxygen and moisture transmission, which prolongs food freshness and shelf life. PVDC's enhanced impermeability makes it the preferred choice for high-performance food packaging requiring extended preservation.

Clarity and Transparency: Visual Appeal

Polyvinyl chloride (PVC) offers excellent clarity and high transparency, making it ideal for food wrap where visual appeal is crucial to showcase fresh products. Polyvinylidene chloride (PVDC) provides moderate clarity but superior barrier properties, which can slightly reduce transparency compared to PVC. For applications prioritizing vibrant, clear presentation, PVC is typically preferred due to its sharper, glass-like appearance.

Flexibility and Cling Performance

Polyvinyl chloride (PVC) film offers superior flexibility, allowing it to conform tightly to various food shapes and surfaces for effective sealing. Polyvinylidene chloride (PVDC) provides excellent cling performance with a more durable, moisture-resistant barrier, making it ideal for extended food preservation. While PVC excels in stretchability and ease of use, PVDC's superior barrier properties enhance food freshness and shelf life.

Safety and Food Contact Regulations

Polyvinyl chloride (PVC) and polyvinylidene chloride (PVDC) are widely used food wrap materials, but PVDC offers superior barrier properties against oxygen and moisture, enhancing food preservation. From a safety and food contact regulation perspective, both PVC and PVDC must comply with FDA and EU standards, though PVC often requires plasticizers such as phthalates, which have raised health concerns and regulatory scrutiny. PVDC is generally considered safer for direct food contact due to fewer additives, and its strong chemical resistance minimizes the risk of harmful migration into food.

Environmental Impact and Sustainability

Polyvinyl chloride (PVC) food wrap is less environmentally friendly due to its chlorine content, which can release toxic dioxins during production and disposal, complicating recycling efforts and increasing pollution. Polyvinylidene chloride (PVDC), while offering superior barrier properties for food preservation, also poses environmental challenges because it is less recyclable and breaks down slowly, contributing to plastic waste. Both materials highlight the need for innovative, sustainable alternatives in food packaging to reduce ecological footprints and improve waste management.

Cost Considerations and Market Availability

Polyvinyl chloride (PVC) food wrap is generally more cost-effective than polyvinylidene chloride (PVDC) due to its lower production expenses and widespread manufacturing. PVC offers broad market availability with numerous suppliers, making it a preferred choice for budget-conscious consumers and businesses. PVDC, while superior in barrier properties and shelf-life extension, tends to be pricier and less commonly stocked, limiting its accessibility in standard retail markets.

Conclusion: Choosing the Right Food Wrap Material

Polyvinyl chloride (PVC) offers strong cling and flexibility, making it ideal for everyday food wrapping but raises concerns due to potential chemical migration. Polyvinylidene chloride (PVDC) provides superior oxygen and moisture barriers, enhancing food preservation and extending shelf life, though it is less flexible and costlier. Selecting the right food wrap depends on balancing cost, performance requirements, and health considerations, with PVDC preferred for high-barrier needs and PVC favored for general use.

Polyvinyl chloride vs. polyvinylidene chloride for food wrap - What is The Difference?

Infographic: Polyvinyl chloride vs Polyvinylidene chloride for Food Wrap



About the author. Kakani is a respected author and expert in materials for industrial and manufacturing applications. With years of experience in both research and industry.

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