Polyethylene terephthalate vs. Polyvinylidene chloride for food wrap - What is The Difference?

Last Updated May 21, 2025

Polyethylene terephthalate (PET) offers excellent clarity, high tensile strength, and superior gas barrier properties ideal for food wrap applications. Polyvinylidene chloride (PVDC) provides exceptional chemical resistance and moisture barrier, making it highly effective for preserving food freshness in packaging.

Table of Comparison

Property Polyethylene Terephthalate (PET) Polyvinylidene Chloride (PVDC)
Material Type Thermoplastic polyester Chlorinated vinyl polymer
Common Use Food packaging, beverage bottles, food wrap Food wrap, barrier films for food preservation
Gas Barrier Moderate oxygen and moisture barrier Excellent oxygen and moisture barrier
Moisture Resistance Good Superior
Clarity High transparency High transparency, often glossy
Flexibility Moderate High flexibility for cling wrap
Chemical Resistance Good resistance to acids and bases Excellent resistance to chemicals
Temperature Range -40degC to 120degC -30degC to 80degC
Environmental Impact Recyclable, moderate biodegradability Difficult to recycle, low biodegradability
Cost Lower cost, widely available Higher cost due to barrier properties

Overview of Polyethylene Terephthalate (PET) and Polyvinylidene Chloride (PVDC)

Polyethylene Terephthalate (PET) is a strong, lightweight polymer known for its excellent clarity, chemical resistance, and barrier properties against moisture and gases, making it ideal for food packaging. Polyvinylidene Chloride (PVDC) offers superior oxygen and aroma barrier performance, providing extended shelf life for food products by minimizing oxidation and moisture transfer. Both materials are widely used in food wrap applications, with PET favored for its strength and recyclability, while PVDC is chosen for its high barrier efficiency and flexibility.

Material Composition and Structure Comparison

Polyethylene terephthalate (PET) consists of aromatic polyester chains formed by the polymerization of ethylene glycol and terephthalic acid, providing high tensile strength and chemical resistance ideal for food wrap durability. Polyvinylidene chloride (PVDC) is a chlorinated polymer characterized by vinylidene chloride monomers, offering superior oxygen and moisture barrier properties critical for food preservation. PET's semi-crystalline structure ensures clarity and mechanical toughness, whereas PVDC's amorphous nature contributes to flexibility and excellent barrier performance, influencing their respective applications in food packaging.

Barrier Properties: Oxygen, Moisture, and Aroma Protection

Polyethylene terephthalate (PET) offers excellent oxygen barrier properties, making it highly effective in preserving food freshness by preventing oxidation. Polyvinylidene chloride (PVDC) excels in moisture barrier performance, providing superior resistance to water vapor transmission that helps maintain product texture and shelf life. While PET provides good aroma protection, PVDC's enhanced barrier against odor molecules makes it the preferred choice for sensitive food packaging requiring extended aroma retention.

Mechanical Strength and Durability

Polyethylene terephthalate (PET) offers superior mechanical strength compared to polyvinylidene chloride (PVDC), making it more resistant to tearing and punctures in food wrap applications. PET also exhibits higher durability under various temperature conditions, maintaining its integrity during refrigeration and freezing. PVDC provides excellent barrier properties but generally lacks the tensile strength and long-term durability that PET delivers for reliable food packaging.

Transparency and Aesthetic Appeal

Polyethylene terephthalate (PET) offers superior transparency and a high-gloss finish, making it an excellent choice for food wrap with enhanced aesthetic appeal that showcases the product clearly. Polyvinylidene chloride (PVDC), while providing strong barrier properties, tends to have a slightly hazier appearance, which can reduce overall clarity and visual attractiveness. PET's natural clarity allows for a sleek, modern presentation preferred in retail packaging, emphasizing product visibility and consumer appeal.

Food Safety and Regulatory Compliance

Polyethylene terephthalate (PET) and Polyvinylidene chloride (PVDC) both serve as food wrap materials with distinct food safety profiles and regulatory statuses. PET is widely recognized for its chemical stability, FDA approval for direct food contact, and resistance to moisture and oxygen, making it suitable for preserving food freshness and preventing contamination. PVDC offers superior barrier properties against oxygen and moisture but faces stricter regulatory scrutiny due to concerns about chlorine content and potential formation of harmful byproducts during disposal, thereby necessitating careful compliance with regional food safety regulations.

Environmental Impact and Recyclability

Polyethylene terephthalate (PET) offers superior recyclability compared to polyvinylidene chloride (PVDC), as PET is widely accepted in recycling programs and can be reprocessed into new packaging materials with lower energy consumption. PVDC poses environmental challenges due to its chlorine content, which complicates recycling and can release harmful dioxins during incineration. PET's lower environmental impact and better recyclability make it a more sustainable choice for food wrap applications, reducing landfill waste and supporting circular economy initiatives.

Cost Analysis and Market Availability

Polyethylene terephthalate (PET) offers a cost-effective solution for food wrap due to its low production costs and widespread availability compared to polyvinylidene chloride (PVDC), which is more expensive due to complex manufacturing processes and limited suppliers. Market availability of PET is significantly higher, supported by large-scale production and global distribution networks, making it the preferred choice for food packaging manufacturers aiming to balance quality and cost. PVDC, although superior in barrier properties against moisture and oxygen, faces constraints in market penetration due to higher prices and fewer commercial producers.

Common Applications in Food Packaging

Polyethylene terephthalate (PET) is widely used for food packaging applications requiring high clarity, excellent barrier properties against moisture and gases, and strong mechanical strength, such as beverage bottles, salad clamshells, and microwaveable trays. Polyvinylidene chloride (PVDC) excels in providing superior oxygen and aroma barrier properties, making it ideal for packaging perishable foods like deli meats, cheese, and bakery products to extend shelf life. Both materials are chosen in food wrap applications based on their barrier performance, transparency, and flexibility, with PET favored for rigid containers and PVDC commonly utilized in flexible films and laminates.

Choosing the Best Food Wrap Material: PET vs PVDC

Polyethylene terephthalate (PET) offers superior clarity, chemical resistance, and recyclability, making it ideal for food packaging that requires high visibility and environmental considerations. Polyvinylidene chloride (PVDC) provides excellent barrier properties against moisture, oxygen, and aromas, enhancing food preservation and shelf life. Choosing between PET and PVDC depends on prioritizing transparency and sustainability with PET or superior barrier protection with PVDC for extended freshness.

Polyethylene terephthalate vs. Polyvinylidene chloride for food wrap - What is The Difference?

Infographic: Polyethylene terephthalate vs Polyvinylidene chloride for Food Wrap



About the author. Kakani is a respected author and expert in materials for industrial and manufacturing applications. With years of experience in both research and industry.

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